A MAGNETIC CIRCULAR-DICHROISM STUDY OF COBALT ATOMS IN A XENON MATRIX

被引：0
|
作者：
ROSER, D [1 ]
VALA, M [1 ]
机构：
[1] UNIV FLORIDA,CTR CHEM PHYS,GAINESVILLE,FL 32611
来源：
CHEMICAL PHYSICS LETTERS | 1993年 / 205卷 / 01期
关键词：
D O I：
10.1016/0009-2614(93)85158-K
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cobalt atoms have been deposited in a xenon matrix at 12 K using pulsed Nd/YAG laser ablation and subsequently studied via magnetic circular dichroism and absorption spectroscopy. This study reveals that several assignments of the electronic transitions of vapor phase Co are in error. It is proposed that the z4G11/2 and zF-4(7/2) states should be exchanged. With this interchange, it is shown that better agreement with the Lande interval rule is obtained for both z4G and zF-4 manifolds.
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页码：6 / 12
页数：7
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