CRYSTAL-STRUCTURES OF [H4L] (CLO4)4.6H2O AND [ZN(H2L)(S2O6)2].4H2O (L = 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE)

被引：24

作者：

BERNHARDT, PV ^{[1
]}

HAMBLEY, TW ^{[1
]}

LAWRANCE, GA ^{[1
]}

机构：

[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 04期

关键词：

D O I：

10.1071/CH9900699

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The substituted macrocycle 6, 13-dimethyi-l, 4, 8, ll-tetraazacyclotetradecane-6, 13-diamine (L) can be crystallized as the perchlorate salt or the zinc dithionate complex. The crystal structures of [H4L](CIO4)4.6H2O (1) and [Zn(H2L)(S2O6)2].4H2O (2) have been determined by X-ray diffraction methods and refined to a residual of 0·058 for 1926 independent observed reflections for (1) and 0·022 for 2122 independent reflections for (2). The crystals of (1) are monoclinic, P21/c, a 10·657(2), b 12·466(7), c 12·216(3) Å, β 96·73(2)° and those of (2) are monoclinic, P21/c, a 8·521(1), b 12·990(1), c 12·731(1) Å, β 105·45(1)°. The pendant primary amines in the zinc(II) complex of L are protonated and not coordinated, with conformational geometry very similar in both structures. © 1990 ASEG.

引用

页码：699 / 706

页数：8

共 50 条

[11] The Crystal Structure of Indium Perchlorates [In(H2O)6](ClO4)3 and [In(H2O)6](ClO4)3 • 3H2O
Ilyukhin, A. B.
Malyarik, M. A.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (04) : 476 - 479
[12] Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) • 4H2O] n
Larionov, S. V.
Myachina, L. I.
Klevtsova, R. F.
Glinskaya, L. A.
Kurat'eva, N. V.
Uskov, E. M.
Rakhmanov, M. I.
Karpov, V. M.
Platonov, V. E.
Fadeeva, V. P.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (09) : 650 - 656
[13] Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H2L). Crystal structure of coordination polymer [Zn(H2O)4(L) · 4H2O]n
S. V. Larionov
L. I. Myachina
R. F. Klevtsova
L. A. Glinskaya
N. V. Kurat’eva
E. M. Uskov
M. I. Rakhmanov
V. M. Karpov
V. E. Platonov
V. P. Fadeeva
Russian Journal of Coordination Chemistry, 2011, 37 : 650 - 656
[14] Revision of the Mg(ClO4)2•4H2O crystal structure
Solovyov, Leonid A.
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2012, 68 : 89 - 90
[15] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
Zheng, YQ
Kong, ZP
JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
[16] A novel trinuclear nickel(II) phenanthroline suberato complex:: {Ni[Ni(phen)(H2O)4]2L4/2}L•4H2O (H2L = suberic acid)
Zheng, YQ
Lin, JL
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (08): : 1724 - 1726
[17] ALKALINE-EARTH-METAL COMPLEXES OF 1,4,8,11-TETRAAZACYCLOTETRADECANE-1,4,8,11-TETRAACETIC ACID, H4TETA, AND CRYSTAL AND MOLECULAR-STRUCTURE OF H4TETA.6H2O AND [MG(H2TETA)(H2O)4].4H2O
MAURYA, MR
ZALUZEC, EJ
PAVKOVIC, SF
HERLINGER, AW
INORGANIC CHEMISTRY, 1991, 30 (19) : 3657 - 3662
[18] CRYSTAL STRUCTURE OF COMPLEX OF ERBIUM（Ⅲ） AND QLYCINE,[Er（GLy）2（H2O）4]2（ClO4）6·4（C4H8O2）
Zheng Yifan Pan KezhenFujian Institute of Research on the Structure of Matter
结构化学, 1987, (02) : 132 - 134
[19] 3-(diallylamino)propanenitrile ((C3H5)2NC2H4CN, L) π-complexes with copper(I) ionic salts. Syntheses and crystal structures of compounds [Cu(H+L)ClO4]ClO4 · H2O, [Cu(H+L)BF4]BF4 · H2O, and [Cu(H+L)(H2O)]SiF6 · H2O
M. Yu. Luk’yanov
A. V. Pavlyuk
E. A. Goreshnik
M. G. Mys’kiv
Russian Journal of Coordination Chemistry, 2012, 38 : 639 - 645
[20] 3-(diallylamino)propanenitrile ((C3H5)2NC2H4CN, L) π-complexes with copper(I) ionic salts. Syntheses and crystal structures of compounds [Cu(H+L)ClO4]ClO4 • H2O, [Cu(H+L)BF4]BF4 • H2O, and [Cu(H+L)(H2O)]SiF6 • H2O
Luk'yanov, M. Yu
Pavlyuk, A. V.
Goreshnik, E. A.
Mys'kiv, M. G.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (09) : 639 - 645

← 1 2 3 4 5 →