SYNTHESIS AND CHARACTERIZATION OF THORIUM(IV) AND DIOXOURANIUM(VI) COMPLEXES OF PENTAMETHYLENE SULFOXIDE

被引：10
|
作者：
AGARWAL, RK
PRAKASH, J
机构：
[1] Postgraduate Department of Chemistry, Lajpat Rai Postgraduate College, Meerut University, Sahibabad
来源：
POLYHEDRON | 1991年 / 10卷 / 22期
关键词：
D O I：
10.1016/S0277-5387(00)81331-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Some thorium(IV) and dioxouranium(VI) complexes with pentamethylene sulphoxide (PMSO) of the general composition [ThX4(PMSO)n] (X = Cl, Br, NO3 or NCS, n = 2; X = I, n = 4; X = ClO4, n = 6) and [UO2X2(PMSO)n] (X = Cl, Br, I, NO3, NCS or CH3COO,n = 2; X = ClO4, n = 4) were synthesized and characterized by IR, conductivity, molecular weight and analytical techniques. In all the complexes the PMSO is coordinated to the metal ion via its oxygen donor atom. The thermal properties of the complexes are also reported.
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收藏
页码：2567 / 2571
页数：5
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