SOLUBILITY OF ANTHRACENE IN BINARY ALKANE PLUS 3-METHYL-1-BUTANOL SOLVENT MIXTURES

被引:18
|
作者
ZVAIGZNE, AI [1 ]
ACREE, WE [1 ]
机构
[1] UNIV N TEXAS, DEPT CHEM, DENTON, TX 76203 USA
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D O I
10.1021/je00016a015
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental solubilities are reported for anthracene dissolved in seven binary mixtures containing 3-methyl-1-butanol with hexane, heptane, octane, cyclohexane, methylcyclohexane, 2,2,4-trimethylpentane, and tert-butylcyclohexane at 25-degrees-C. Results of these measurements are used to test two mathematical representations based upon the combined nearly ideal binary solvent (NIBS)/Redlich-Kister equation and modified Wilson model. For the systems studied, the combined NIBS/Redlich-Kister and modified Wilson equations were found to provide very reasonable mathematical representations, with deviations between experimental and back-calculated values being on the order of +/- 1.5% or less.
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页码:708 / 710
页数:3
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