EINSTEIN COEFFICIENTS FOR ROTATIONAL LINES OF THE (0, 0) BAND OF THE NO A2-SIGMA+-X2-PI SYSTEM

被引:68
|
作者
REISEL, JR
CARTER, CD
LAURENDEAU, NM
机构
[1] Flame Diagnostics Laboratory, School of Mechanical Engineering, Purdue University, West Lafayette
基金
美国国家航空航天局;
关键词
D O I
10.1016/0022-4073(92)90078-I
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
We present a summary of the spectroscopic equations necessary for prediction of the molecular transition energies and the Einstein A and B coefficients for rovibronic lines of the gamma(0, 0) band of nitric oxide (NO). The calculated molecular transition energies are all within 0.57 cm-1 of published experimental values; in addition, over 95% of the calculated energies give agreement with measured results within 0.25 cm-1. Einstein A(J' J'') and B(J'' J') coefficients are calculated from the band A00 value and the known Honl-London factors and are tabulated for individual rovibronic transitions in the NO A2-SIGMA+-X2-PI(0, 0) band.
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页码:43 / 54
页数:12
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