USE OF NAPHTHALENE AS A SOLVENT FOR SELECTIVE FORMATION OF THE 1/1 DIELS-ALDER ADDUCT OF C-60 WITH ANTHRACENE

被引：117
|
作者：
KOMATSU, K
MURATA, Y
SUGITA, N
TAKEUCHI, K
WAN, TSM
机构：
[1] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG
[2] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期
关键词：
D O I：
10.1016/S0040-4039(00)61362-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A reaction of C-60 with an equimolar amount of anthracene in refluxing naphthalene gives the 1:1 Diels-Alder adduct in 67% yield based on consumed C-60: the adduct was fully characterized by IR, UV-vis, H-1 and C-13 NMR, and MS spectroscopy, and exhibited reversible reduction waves at the potential 0.11 to 0.19 V more negative and an irreversible oxidation peak at the potential 0.11 V less positive than those of C-60 itself.
引用
收藏
页码：8473 / 8476
页数：4
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