BOND CHARACTER IN LIQUID ALLOYS FROM MAGNETIC-SUSCEPTIBILITY

被引：2

作者：

OTT, K ^{[1
]}

DURRWACHTER, M ^{[1
]}

HAGHANI, MA ^{[1
]}

QUITMANN, D ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST EXPTL PHYS,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1992年 / 142卷 / 03期

关键词：

D O I：

10.1016/S0022-3093(05)80034-1

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A model of assumed reactions mu-A+nu-B reversible A(mu)B(nu) has proven very useful in liquid alloys with strong A-B bonding, where it describes thermodynamics (DELTA-H, etc.), Knight shifts and quadrupolar relaxation. It is here applied to discuss the contributions to the magnetic susceptibility, made by the right-hand side state of the reaction (A(mu)B(nu)). By combining with a description of the susceptibility as a function of the degree of covalency in crystalline compounds, an estimate of that degree for the A-B bonds in several liquid-metal-Te alloys is derived. Thus it becomes possible to place them on a bond character chart.

引用

页码：278 / 286

页数：9

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