NUCLEAR-CHEMICAL GENERATION OF FREE PHENYLNITRENIUM CATIONS

被引：0
|
作者：
NEFEDOV, VD
TOROPOVA, MA
SIMONOVA, TP
ZHURAVLEV, VE
VORONTSOV, AM
机构：
来源：
SOVIET RADIOCHEMISTRY | 1990年 / 32卷 / 01期
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D O I：
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中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A nuclear-chemical method for generating free phenylnitrenium ions (without counter ions or a solvation sphere) is proposed. It is based on beta-decay of tritium in the aniline amino group. The reactivity of four reaction centers of the phenylnitrenium cation is demonstrated using the ion-molecule reaction of these cations. Ultramicroquantities of the reaction products of phenylnitrenium ions with benzene (diphenylamine, ortho- and para-aminobiphenyl) are separated chromatographically.
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页码：57 / 59
页数：3
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