HIGHLY-CONDUCTING LANGMUIR-BLODGETT-FILMS OF AN AMPHIPHILIC BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE (BEDT-TTF) DERIVATIVE - BEDT-TTF-C18H37

被引：32
|
作者：
GOLDENBERG, LM
KHODORKOVSKY, VYT
BECKER, JY
LUKES, PJ
BRYCE, MR
PETTY, MC
YARWOOD, J
机构：
[1] BEN GURION UNIV NEGEV,DEPT CHEM,IL-84120 BEER SHEVA,ISRAEL
[2] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
[3] UNIV DURHAM,SCH ENGN & COMP SCI,DURHAM DH1 3LE,ENGLAND
[4] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND
来源：
CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 08期
关键词：
D O I：
10.1021/cm00044a047
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Langmuir-Blodgett films of (octadecylethylenedithio)(ethylenedithio)tetrathiafulvalene (1, BEDT-TTF-C18H37), mixed with 10-20% tricosanoic or stearic acid, have room-temperature conductivity values as high as sigma(rt) = 10(-1) S cm-1 as-deposited, and sigma(rt) = 1.0 S cm-1 after iodine doping. Moreover, these values are stable upon storage of the films for up to 4 weeks in air. The LB films have been characterized by UV-visible and IR spectroscopy and by cyclic voltammetry.
引用
收藏
页码：1426 / 1431
页数：6
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