STRUCTURAL AND ELECTRONIC-PROPERTIES OF A NEW TWO-DIMENSIONAL MOLECULAR-METAL, ET2ME2N[NI(DMIT)2]2

被引：0
|
作者：
KATO, R
KOBAYASHI, H
KIM, H
KOBAYASHI, A
SASAKI, Y
MORI, T
INOKUCHI, H
机构：
[1] UNIV TOKYO,FAC SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN
[2] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN
来源：
SYNTHETIC METALS | 1988年 / 27卷 / 3-4期
关键词：
Crystals--Structure;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Structural and electronic properties of the anion radical salts M[Ni(dmit)2]2(dmit= 4,5-dimercapto-1,3-dithiole-2-thione; M=Et2Me2N, EtMe3N, Me4P, Me4As, Me4Sb, Me3S(O), Me3S) have been investigated. Among them, α-Et2Me2N[Ni(dmit)2]2 retains metallic behavior down to 1.5 K. In the crystal of α-Et2Me2N[Ni(dmit)2]2, planar Ni(dmit)2 units are stacked in such a way that one molecule overlaps with two molecules. Such a spanning overlap mode has provided a two-dimensional electronic structure. This compound is the first two-dimensional metal derived from the π-acceptor molecule.
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页码：B359 / B364
页数：6
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