CONFIGURATIONAL STABILITY OF CHIRAL ORGANOLITHIUM COMPOUNDS ON THE TIME-SCALE OF THEIR ADDITION TO ALDEHYDES

被引：0
|
作者：
HOFFMANN, RW [1 ]
JULIUS, M [1 ]
CHEMLA, F [1 ]
RUHLAND, T [1 ]
FRENZEN, G [1 ]
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY
来源：
TETRAHEDRON | 1994年 / 50卷 / 20期
关键词：
CONFIGURATIONAL STABILITY; ORGANOLITHIUM COMPOUNDS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A test based on kinetic resolution has been applied to the alpha-bromo-, alpha-phenylseleno- and alpha-phenylthio-alkyl-lithium compounds 1, which shows that addition of these species to the chiral aldehyde 6 occurs faster than enantiomer equilibration of the organolithium compounds.
引用
收藏
页码：6049 / 6060
页数：12
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