EFFECT OF PROTEIN ENVIRONMENT ON THE ELECTRON STATE AND ELECTRON-TRANSFER IN METALLOPROTEINS

被引：0
|
作者：
CHUEV, GN [1 ]
机构：
[1] RUSSIAN ACAD SCI,COMP RES CTR,PUSHCHINO,USSR
来源：
TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1992年 / 28卷 / 02期
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The calculations, of energy and electron wave functions for the ground and excited self-consisted states at active site cyt C are given on the base of semicontinium method, allowing for both the molecular structure of the site and the effect of protein surroundings. Reorganization energy, matrix element and transfer rate constant are calculated for investigated electron states in self-exchange cyt C reaction. Calculations satisfactorily agree with experimental data.
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页码：180 / 183
页数：4
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