LISR2[CON2] - A NITRIDOCOBALTATE(I) WITH LINEAR ANIONS [CON2]5-

被引：0
|
作者：
HOHN, P
KNIEP, R
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 03期
关键词：
NITRIDOCOBALTATE(I); PREPARATION; CRYSTAL STRUCTURE; STRUCTURAL RELATIONS;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
LiSr2[CoN2] (tetrag., P4(2)/mnm (Nr. 136); a = 524.4(1) pm, c = 730.7(2) pm; Z = 2) was prepared by reaction of mixtures of Li, Sr2N and Co (molar ratio 6:3:1) in tantalum crucibles under nitrogen (1 atm) at 850-degrees-C. The crystal structure (alpha-Li3[BN2]-type) contains linear anions [CoIN2]5- (Co-N: 181.0(5) pm) which are isostructural to [FeIIN2]4- (Li4[FeN2]) as well as to the maingroup species CO2 and [BN2]3-.
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页码：434 / 436
页数：3
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