[CoN2]/[CN2]-Substitution in a Crystalline Phase with Composition Close to Sr6[CoN2]2[CN2]

被引：2

作者：

Bendyna, Joanna K. ^{[1
]}

Hoehn, Peter ^{[1
]}

Prots, Yurii ^{[1
]}

Kniep, Ruediger ^{[1
]}

机构：

[1] Max Planck Inst Chem Phys Fester Stoffe, D-01187 Dresden, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 07期

关键词：

Nitridometalates; Carbodiimides; Strontium; Cobalt; Disorder;

D O I：

10.1002/zaac.201000035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sr-6[CoN2](2)[CN2] was prepared from Sr2N, carbon, cobalt, and NaN3 as nitrogen source. The crystal structure (14/mmm (no. 139), a = 383.55(10) pm, c = 1237.8(4) pm) represents a Na-2[HgO2] type arrangement with both linear [(CoN2)-N-I](5-) and smaller [CN2](2-) ions mutually occupying the [HgO2] position.

引用

页码：1297 / 1300

页数：4

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