SYNTHESIS AND CRYSTAL-STRUCTURE OF A RUTHENIUM COMPLEX CONTAINING 2 MONODENTATE DPPM LIGANDS (DPPM=BIS(DIPHENYLPHOSPHINO)METHANE)

被引：11
|
作者：
BARRAL, MC
JIMENEZAPARICIO, R
ROYER, EC
SAUCEDO, MJ
URBANOS, FA
GUTIERREZPUEBLA, E
RUIZVALERO, C
机构：
[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM INORGAN,E-28040 MADRID,SPAIN
[2] CSIC,INST CIENCIAS MAT,E-28006 MADRID,SPAIN
[3] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,LAB RAYOS X,E-28040 MADRID,SPAIN
来源：
INORGANICA CHIMICA ACTA | 1993年 / 209卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)84989-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds trans-Ru(quin)2(dppm)2 and cis- and trans-Ru(quin)2(PPh3)2 (quin=2-quinaldinate anion; dppm=bis(diphenylphosphino)methane) have been prepared by the reaction of RuCl3.3H2O and Hquin, in basic alcoholic medium, in the presence of dppm and PPh3, respectively. The compounds are characterized by elemental analysis, IR, H-1 and P-31{H-1} NMR spectroscopy. The structure of trans-Ru(quin)2(dppm)2.2MeOH has been determined by X-ray crystallography. The compound has two bidentate N,O-quinaldinate and two monodentate dppm ligands in a trans-N, trans-O, trans-P arrangement.
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页码：105 / 109
页数：5
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