Synthesis and X-ray structure of [(μ-H)Ru3(CO)8(μ-Cl)(μ-dppm)] [dppm = bis(diphenylphosphino)methane]

被引：0
|
作者：
Mohammad R. Hasan
Michael B. Hursthouse
Shariff E. Kabir
K.M. Abdul Malik
Edward Rosenberg
Tasneem A. Siddiquee
机构：
[1] Jahangirnagar University,Department of Chemistry
[2] Cardiff University,Department of Chemistry
[3] University of Southampton,Department of Chemistry
来源：
Journal of Chemical Crystallography | 1999年 / 29卷
关键词：
ruthenium cluster; bis(diphenylphosphino)methane; hydride; chloride; X-ray structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of [Ru3(CO)10(μ-dppm)] 1 with PPhCl2 in refluxing CHCl3 results in the isolation of [(μ-H)Ru3(CO)8(μ-Cl)(μ-dppm)] 3 in 10% yield. Compound 3, which has been structurally characterized by crystallographic methods, is also formed from the reaction of 1 with H2 in refluxing CCl4. The compound crystallizes in the monoclinic space group P21/c with a = 16.814(2), b = 18.7590(12), c = 11.486(2) Å, β = 97.745(11)°, V = 3589.8(8) Å3, and Z = 4. The hydride and chloride ligands bridge the same edge of the triruthenium cluster as the dppm ligand.
引用
收藏
页码：597 / 602
页数：5
相关论文
共 50 条
  • [1] Synthesis and X-ray structure of [(μ-H)Ru3(Co)8(μ-Cl)(μ-dppm)] [dppm = bis(diphenylphosphino)methane]
    Hasan, MR
    Hursthouse, MB
    Kabir, SE
    Malik, KMA
    Rosenberg, E
    Siddiquee, TA
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1999, 29 (05) : 597 - 602
  • [2] Thermolysis of Ru3(CO)8(μ-dPPm)(μ-dpam): Transformation of bis(diphenylphosphino)methane and bis(diphenylarsino)methane
    Sirat, Siti Syaida
    Bin Shawkataly, Omar
    Razak, Ibrahim Abdul
    [J]. POLYHEDRON, 2018, 155 : 493 - 499
  • [3] REACTIONS OF PD(IV) WITH NABH4 IN THE PRESENCE OF BIS(DIPHENYLPHOSPHINO)-METHANE (DPPM) AND CO - THE X-RAY STRUCTURE OF PD6(CO)6(DPPM)3
    HOLAH, DG
    HUGHES, AN
    KRYSA, E
    MAGNUSON, VR
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 59 - INOR
  • [4] SPECTROSCOPY AND X-RAY CRYSTAL-STRUCTURE OF LUMINESCENT PT2(DPPM)2(CN)4[DPPM = BIS(DIPHENYLPHOSPHINO)METHANE]
    CHE, CM
    YAM, VWW
    WONG, WT
    LAI, TF
    [J]. INORGANIC CHEMISTRY, 1989, 28 (15) : 2908 - 2910
  • [5] SYNTHESIS AND STRUCTURE OF THE CLUSTER [TRIANGULO-AGHG2(MU-DPPM)(3)](3+)[ DPPM=BIS(DIPHENYLPHOSPHINO)METHANE]
    KNOEPFLER, A
    WURST, K
    PERINGER, P
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (02) : 131 - 132
  • [6] Synthesis and structures of oxyanion encapsulated copper(I)-dppm complexes (dppm = bis(diphenylphosphino)methane)
    Bera, JK
    Nethaji, M
    Samuelson, AG
    [J]. INORGANIC CHEMISTRY, 1999, 38 (08) : 1725 - 1735
  • [7] Synthesis, Characterization, and X-ray Crystal Structures of Ru3(CO)9(dppm)AsPh3 and Ru3(CO)9(dpam)PPh3 Complexes
    Bin Shawkataly, Omar
    Khan, Imthyaz Ahmed
    Sirat, Siti Syaida
    Fun, Hoong-Kun
    Rosli, Mohd Mustaqim
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (07): : 1397 - 1402
  • [8] SYNTHESIS AND CRYSTAL-STRUCTURE OF A RUTHENIUM COMPLEX CONTAINING 2 MONODENTATE DPPM LIGANDS (DPPM=BIS(DIPHENYLPHOSPHINO)METHANE)
    BARRAL, MC
    JIMENEZAPARICIO, R
    ROYER, EC
    SAUCEDO, MJ
    URBANOS, FA
    GUTIERREZPUEBLA, E
    RUIZVALERO, C
    [J]. INORGANICA CHIMICA ACTA, 1993, 209 (01) : 105 - 109
  • [9] Synthesis and Structure of the Cluster [triangulo-AgHg2(ae-dppm)3]3+ [dppm = bis-(diphenylphosphino)methane]
    Knoepfler, A.
    Wurst, K.
    Peringer, P.
    [J]. Zeitschrift fuer Physik D: Atoms, Molecules and Clusters, 330
  • [10] Triruthenium clusters bearing bridging dppm and capping sulfido ligands:: X-ray structures of [Ru3(CO)6(μ3-CO)(μ3-S)(PPh3)(μ-dppm)] and [Ru3(CO)6(μ3-S)2(PPh3)(μ-dppm)]
    Hyder, MI
    Hossain, GMG
    Kabir, SE
    Miah, MA
    [J]. POLYHEDRON, 2005, 24 (08) : 872 - 880
12345