NOVEL CHIRAL DOPANTS FROM OPTICALLY-ACTIVE 2.4-PENTANEDIOL

被引：1

作者：

SHIBATA, T ^{[1
]}

KIMURA, M ^{[1
]}

TAKANO, S ^{[1
]}

OGASAWARA, K ^{[1
]}

机构：

[1] TOUHOKU UNIV,SENDAI,MIYAGI 111,JAPAN

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1993年 / 237卷

关键词：

CHIRAL DOPANT; OPTICALLY ACTIVE 2.4-PENTANEDIOL; HELICAL PITCH;

D O I：

10.1080/10587259308030161

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A variety of chiral dopants from optically active 2.4-pentanediol (A) were prepared. [GRAPHICS] The temperature coefficient of induced cholesteric pitch of these materials (dP/dT) was measured to show that dP/dT depended on substituent group X. When X = Cl, compound (A) shows a short induced helical pitch and dP/dT = 0. Acetoxy and methoxy derivatives show negative dP/dT. Furthermore, when X = OH, compound (A) shows positive dP/dT.

引用

页码：483 / 485

页数：3

共 50 条

[31] SYNTHESIS AND PROPERTIES OF OPTICALLY-ACTIVE ALPHA-TRIFLUOROMETHYLBENZYL DERIVATIVES AS NEW CHIRAL DOPANTS FOR FERROELECTRIC LIQUID-CRYSTALS
AOKI, Y
NOHIRA, H
CHEMISTRY LETTERS, 1993, (01) : 113 - 116
[32] MANIFESTATION OF CHIRAL ASYMMETRY OF FERROELECTRIC LIQUID-CRYSTALS INDUCED BY OPTICALLY-ACTIVE DIPOLE DOPANTS IN A LINEAR ELECTROOPTIC EFFECT
RABINOVICH, AZ
LOSEVA, MV
CHERNOVA, NI
POZHIDAEV, EP
PETRASHEVICH, OS
NARKEVICH, JS
LIQUID CRYSTALS, 1989, 6 (05) : 533 - 543
[33] NEW OPTICALLY-ACTIVE 4,4-DIALKYL-GAMMA-LACTONES AS CHIRAL DOPANTS FOR FERROELECTRIC LIQUID-CRYSTALS
IKEMOTO, T
SAKASHITA, K
KAGEYAMA, Y
TERADA, F
NAKAOKA, Y
ICHIMURA, K
MORI, K
CHEMISTRY LETTERS, 1992, (04) : 567 - 570
[34] AN OPTICALLY-ACTIVE STEREOREGULAR POLYPHENYLACETYLENE DERIVATIVE AS A NOVEL CHIRAL STATIONARY-PHASE FOR HPLC
YASHIMA, E
HUANG, SL
OKAMOTO, Y
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (15) : 1811 - 1812
[35] SYNTHESIS AND PROPERTIES OF OPTICALLY-ACTIVE 1,3-DIOLS AND THEIR DERIVATIVES AS CHIRAL DOPANTS FOR FERROELECTRIC LIQUID-CRYSTALS
KUSUMOTO, T
SATO, K
OGINO, K
HIYAMA, T
TAKEHARA, S
OSAWA, M
NAKAMURA, K
LIQUID CRYSTALS, 1993, 14 (03) : 727 - 732
[36] Preparation of novel optically active carboxylic acids and application as chiral dopants for nematic liquid crystals
Shitara, Hiroaki
Aoki, Yoshio
Nohira, Hiroyuki
Hirose, Takuji
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2006, 64 (10) : 1032 - 1040
[37] Synthesis of novel chiral dopants based on optically active p-substituted mandelic acids
Lesac, A
Narancic, S
Sepelj, M
Bruce, DW
Sunjic, V
TETRAHEDRON-ASYMMETRY, 2003, 14 (18) : 2731 - 2737
[38] OPTICALLY-ACTIVE ARYLPROPIONIC ACIDS FROM THE STEREOSELECTIVE ALKYLATION OF CHIRAL IMIDE ENOLATES
FADEL, A
SYNLETT, 1992, (01) : 48 - 50
[39] PRACTICAL PREPARATION OF OPTICALLY-ACTIVE O-BENZYLGLYCIDOL FROM OPTICALLY-ACTIVE EPICHLOROHYDRIN
TAKANO, S
SEKIGUCHI, Y
SETOH, M
YOSHIMITSU, T
INOMATA, K
TAKAHASHI, M
OGASAWARA, K
HETEROCYCLES, 1990, 31 (09) : 1715 - 1719
[40] PREPARATION OF OPTICALLY-ACTIVE NEW MERCAPTO CHIRAL AUXILIARIES DERIVED FROM CAMPHOR
LEE, DS
HUNG, SM
LAI, MC
CHU, HY
YANG, TK
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1993, 25 (06) : 673 - 679

← 1 2 3 4 5 →