DELIVERY-CONTROL IN ORGANIC-REACTIVITY

被引：23
|
作者：
SHERROD, MJ [1 ]
MENGER, FM [1 ]
机构：
[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期
关键词：
D O I：
10.1016/0040-4039(90)87007-M
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A large portion of the energy requirements of an intramolecular hydride transfer was shown to entail a carbon skeleton distortion that delivers the hydrogen to the recipient carbon. Only after a critical distance is reached does actual chemical reaction begin. © 1990.
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页码：459 / 462
页数：4
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