STRUCTURAL AND SPECTROSCOPIC CHARACTERIZATION OF A NOVEL VANADIUM(V)-AMIDE COMPLEX

被引：16
|
作者：
CORNMAN, CR
GEISERBUSH, KM
SINGH, P
机构：
[1] Department of Chemistry, North Carolina State University, Raleigh
来源：
INORGANIC CHEMISTRY | 1994年 / 33卷 / 21期
关键词：
D O I：
10.1021/ic00099a008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and X-ray crystal structure of the first structurally characterized vanadium (V) complex containing a vanadium (V)-N-amide bond is reported. The square pyramidal geometry about the central ion contains an oxo, two alkoxide oxygen, and two deprotonated amide nitrogen donor atoms. The vanadium (V) oxidation state is confirmed by the presence of well-resolved H-1 and V-51 NMR signals as well as the absence of an ESR signal.
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页码：4621 / 4622
页数：2
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