THE INFLUENCE OF BRANCHING ON INTERMOLECULAR AND INTRAMOLECULAR INTERACTION PARAMETERS OF POLYMER-SOLVENT SYSTEMS

被引:6
|
作者
IOAN, C [1 ]
IOAN, S [1 ]
SIMIONESCU, BC [1 ]
机构
[1] GH ASACHI TECH UNIV,DEPT MACROMOLEC,R-6600 IASI,ROMANIA
关键词
D O I
10.1080/10601329508013699
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The influence of branching on inter- and intramolecular interaction parameters-as defined by Wolf for linear polymers-is discussed for starlike polystyrene and polybutadiene in good solvents. The paper proposes a method of evaluation of the interaction parameters for branched polymers starting from experimental data on A(2) and [eta] for linear chains and from the theoretical ratios A(2,branched)/A(2,linear) and [eta](branched)/[eta](linear).
引用
收藏
页码:1589 / 1600
页数:12
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