HYDROGEN-BONDED ADDUCTS OF FERROCENE-1,1'-DIYLBIS(DIPHENYLMETHANOL) WITH NITROGENOUS BASES - CRYSTAL AND MOLECULAR-STRUCTURE OF THE 2/1 ADDUCT WITH HEXAMETHYLENETETRAMINE

被引：11

作者：

FERGUSON, G ^{[1
]}

GLIDEWELL, C ^{[1
]}

LEWIS, A ^{[1
]}

ZAKARIA, CM ^{[1
]}

机构：

[1] UNIV GUELPH,DEPT CHEM & BIOCHEM,GUELPH,ON N1G 2W1,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 492卷 / 02期

关键词：

IRON; FERROCENE; HOST-GUEST ADDUCTS; HYDROGEN BONDING; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)05312-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ferrocene-1,1'-diylbis(diphenylmethanol) [Fe(C(5)H(4)CPh(2)OH)(2)] forms hydrogen-bonded host-guest adducts with nitrogenous bases. A 2:1 adduct is formed with hexamethylenetetramine, [(CH2)(6)N-4], 1:1 adducts with 1,4-dimethylpiperazine and 1,4-diazabicyclo [2.2.2]octane and a 1:2 adduct with 3-pyridylferrocene. The crystal structure of the hexamethylenetetramine adduct has been determined. The structural unit contains two molecules of the host ferrocenediol and one molecule of the guest; the diol forms both intramolecular O-H ... O and intermolecular O-H ... N hydrogen bonds, but two of the four nitrogen atoms in the [(CH2)(6)N-4] guest molecules play no part in the hydrogen bonding.

引用

页码：229 / 234

页数：6

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