ISOTHERMAL CRYSTALLIZATION OF ISOTACTIC POLYPROPYLENE IN DOTRIACONTANE .3. EFFECT OF DILUTION AND CRYSTALLIZATION TEMPERATURE ON GROWTH-RATE

被引：20
|
作者：
WANG, YF [1 ]
LLOYD, DR [1 ]
机构：
[1] UNIV TEXAS,CTR POLYMER RES,DEPT CHEM ENGN,AUSTIN,TX 78712
来源：
POLYMER | 1993年 / 34卷 / 11期
关键词：
CRYSTALLIZATION; ISOTACTIC POLYPROPYLENE; KINETICS;
D O I：
10.1016/0032-3861(93)90816-S
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The spherulitic growth rate of isotactic polypropylene in dotriacontane was studied using optical microscopy. Polymer concentration was varied from 100 to 10 wt% iPP in 10 wt% intervals. Crystallization temperature was varied from 372 to 429 K in 1 K intervals. The influence of these variables on polymer spherulitic growth rate and regime transitions was analysed using the Lauritzen-Hoffman and Toda nucleation theories.
引用
收藏
页码：2324 / 2329
页数：6
相关论文
共 50 条
  • [31] Isotactic polypropylene reversible crystallization investigated by modulated temperature and quasi-isothermal FTIR
    Di Lisio, Valerio
    Sturabotti, Elisa
    Francolini, Iolanda
    Piozzi, Antonella
    Martinelli, Andrea
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2019, 57 (14) : 922 - 931
  • [32] Crystallization of isotactic polypropylene under shear flow: Effect of shear rate
    Ogino, Yoshiko
    Matsuba, Go
    Nishida, Koji
    Kanaya, Toshiji
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3711 - U3711
  • [33] Crystallization behavior and spherulite growth rate of isotactic polypropylene in isotactic polypropylene/natural rubber based thermoplastic elastomers
    Joseph, Aju
    Koch, T.
    Seidler, S.
    Thomas, S.
    Joseph, K.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (03) : 1714 - 1721
  • [34] Crystallization behavior and spherulite growth rate of isotactic polypropylene in isotactic polypropylene/natural rubber based thermoplastic elastomers
    Joseph, Aju
    Koch, T.
    Seidler, S.
    Thomas, S.
    Joseph, K.
    Journal of Applied Polymer Science, 2008, 109 (03): : 1714 - 1721
  • [35] RETARDATION OF SPHERULITIC GROWTH-RATE IN THE CRYSTALLIZATION OF ISOTACTIC POLYSTYRENE DUE TO THE PRESENCE OF NUCLEANT
    KENNEDY, MA
    TURTURRO, G
    BROWN, GR
    STPIERRE, LE
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1983, 21 (08) : 1403 - 1413
  • [36] Isothermal crystallization kinetics and morphology development of isotactic polypropylene blends with atactic polypropylene
    Chen, Jean-Hong
    Chang, Yu-Lun
    JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (02) : 1093 - 1104
  • [37] Effect of shear forces on the crystallization of isotactic polypropylene
    Paukszta, Dominik
    Bednarek, Wojciech H.
    PRZEMYSL CHEMICZNY, 2018, 97 (12): : 2038 - 2039
  • [38] The effect of nucleants on the crystallization behavior of isotactic polypropylene
    Budinski-Simendic, J
    Petrovic, Z
    Lazic, V
    Radicevic, R
    Divjakovic, V
    PROGRESS IN ADVANCED MATERIALS AND PROCESSES, 2004, 453-454 : 509 - 514
  • [39] Crystallization of isotactic polypropylene: the effect of fiber surface
    Bogoeva-Gaceva, Gordana
    Grozdanov, Anita
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2006, 71 (05) : 483 - 499
  • [40] The effect of pressure pulses on isotactic polypropylene crystallization
    Zhang, Li
    Van Drongelen, Martin
    Alfonso, Giovanni C.
    Peters, Gerrit W. M.
    EUROPEAN POLYMER JOURNAL, 2015, 71 : 185 - 195
12345