METAL SALT-PROMOTED ALCOHOLYSIS OF 1,2-EPOXIDES

被引:0
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作者
CHINI, M
CROTTI, P
GARDELLI, C
MACCHIA, F
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple, efficient, stereoselective, and regioselective method for the synthesis of beta-alkoxy alcohols by the direct opening of 1,2-epoxides with alcohols (primary, secondary, and tertiary) in a nonprotic solvent or with the alcohol itself as the solvent, in the presence of a metal salt, is described. This new method appears to be competitive with and/or alternative to the other methods previously reported.
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页码:673 / 676
页数:4
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