SOLUBILITY OF AMMONIA IN AQUEOUS-SOLUTIONS OF SODIUM-SULFATE AND AMMONIUM-SULFATE AT TEMPERATURES FROM 333.15 K TO 433.15 K AND PRESSURES UP TO 3-MPA

被引:41
|
作者
RUMPF, B [1 ]
MAURER, G [1 ]
机构
[1] UNIVERSITAT KAISERSLAUTERN,LEHRSTUHL TECH THERMODYNAM,D-67653 KAISERSLAUTERN,GERMANY
关键词
D O I
10.1021/ie00020a036
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
As part of an ongoing project dealing with experimental and theoretical work on phase equilibria in aqueous solutions containing weak electrolyte gases like ammonia, hydrogen cyanide, sulfur dioxide, or carbon dioxide, the solubility of ammonia in aqueous solutions of sodium sulfate and ammonium sulfate was measured by a synthetic method in the temperature range from 333.15 to 433.15 K at total pressures up to 3 MPa. The model proposed by Edwards et al. is used to correlate the data. That model is extended to include the formation of one or more solid phases. Experimental results and the correlations are reported and compared with literature data and other correlations.
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页码:1780 / 1789
页数:10
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