Solubility of hydrogen sulfide in aqueous solutions of the single salts sodium sulfate, ammonium sulfate, sodium chloride, and ammonium chloride at temperatures from 313 to 393 K and total pressures up to 10 MPa

被引:41
|
作者
Xia, JZ [1 ]
Kamps, APS [1 ]
Rumpf, B [1 ]
Maurer, G [1 ]
机构
[1] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67653 Kaiserslautern, Germany
关键词
D O I
10.1021/ie990416p
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
New experimental results for the solubility of hydrogen sulfide in aqueous solutions of the single salts sodium sulfate, ammonium sulfate, sodium chloride, and ammonium chloride at temperatures from 313 to 393 K and total pressures up to 10 MPa are reported. As in the salt-free system, a second-hydrogen sulfide-rich-liquid phase is observed at high hydrogen sulfide concentrations. A model to describe the phase equilibrium is presented. Calculations are compared to the new experimental data.
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页码:1064 / 1073
页数:10
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