A list of 10 species of Laboulbeniales (Fungi, Ascomycotina) from Spain is given. Two species, Phaulomyces denticulatus and Phaulomyces perparvus, are here proposed as new. The other 8 are new records for Spain. Especially remarkable are Corethromyces scopaei and Zeugandromyces orientalis, never recorded from Europe (likewise, the genus Zeugandromyces is new for Europe). Also, Aporomyces szaboi and Ilyomyces mairei are second world records as they were only known from their types. These taxa, along with Cantharomyces denigratus, Cantharomyces italicus, Laboulbenia curtipes and Peyritschiella biformis, are illustrated with line drawings and some new features, not mentioned in previous works are now described and discussed.