SYNTHESIS AND PROPERTIES OF 1,2-DIMETHYLENE-3,5-CYCLOHEPTADIENE

被引：0

作者：

ODA, M ^{[1
]}

KURODA, S ^{[1
]}

SHIMAO, I ^{[1
]}

MORITA, N ^{[1
]}

ASAO, T ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,AOBA KU,SENDAI,MIYAGI 98077,JAPAN

来源：

RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1994年 / 113卷 / 7-8期

关键词：

CYCLOADDITION; THERMAL REARRANGEMENT; CYCLOHEPTATRIENE DERIVATIVE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The regioselective synthesis of dimethyl 1,3,5-cyloheptatriene-1,2-dicarboxylate (4) was achieved by a ring expansion method, starting from dimethyl 1,3-cyclohexadiene-2,3-dicarboxylate (5). The title compound 3 was obtained as an air-sensitive oil by zinc-copper reduction of 1,2-bis(bromomethyl)cyclohepta-1,3,5-tri (10) to which the diester 4 was transformed.

引用

页码：377 / 378

页数：2

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