ENZYMATIC ACYLATION OF METHYL D-GLUCOPYRANOSIDES AND L-GLUCOPYRANOSIDES AND 6-DEOXY-GLUCOPYRANOSIDES

被引:16
|
作者
COLOMBO, D
RONCHETTI, F
SCALA, A
TOMA, L
机构
[1] UNIV MILAN,DIPARTIMENTO CHIM & BIOCHIM MED,VIA SALDINI 50,I-20133 MILAN,ITALY
[2] UNIV PAVIA,DIPARTMENTO CHIM ORGAN,I-27100 PAVIA,ITALY
关键词
D O I
10.1080/07328309208016144
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Methyl 6-O-butyryl-alpha-D- and L-glucopyranosides and methyl 6-deoxy-alpha-D- and L-glucopyranosides have been submitted to lipase catalyzed butyrylation, using porcine pancreatic, Candida cylindracea, and Pseudomonas cepacia lipases in organic solvents. The influence of the orientation of the secondary hydroxyl groups on the regioselectivity of the butyrylation is discussed.
引用
收藏
页码:89 / 94
页数:6
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