EFFECT OF TRANSPORT-INACTIVE COMPONENT ON HOLE TRANSPORT IN ORGANIC-SOLID SOLUTIONS

被引:6
|
作者
YAMAGUCHI, Y
FUJIYAMA, T
TANAKA, H
YOKOYAMA, M
机构
[1] Chemical Process Engineering, Faculty of Engineering, Osaka University Yamadaoka, Suita, Osaka
关键词
D O I
10.1016/0038-1098(91)90514-V
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Hole transport has been investigated in binary solid solutions of N,N,N',N'-tetra(m-tolyl)-1,3-diaminobenzene (PDA) and hole transport-inactive compounds. The mobility in the limit of zero-field obeys the small-polaron hopping theory. The polaron binding energies and the wave-function overlap factors are found to strongly depend on the transport-inactive component. It is suggested that the latter effect is based on the electronic interaction of the frontier orbitals between a charged molecule and the surrounding transport-inactive compounds.
引用
收藏
页码:817 / 820
页数:4
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