THE ASYMMETRIC-SYNTHESIS OF 2-BROMOHOMOALLYLIC ALCOHOLS USING THE TARTRATE ESTER OF (2-BROMOALLYL)BORONIC ACID PREPARED BY BROMOBORATION REACTION OF ALLENE

被引：0

作者：

HARA, S ^{[1
]}

YAMAMOTO, Y ^{[1
]}

FUJITA, A ^{[1
]}

SUZUKI, A ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI,DEPT APPL CHEM,OKAYAMA 700,JAPAN

来源：

SYNLETT | 1994年 / 08期

关键词：

BROMOBORATION; TARTRATE ESTER; 2-BROMOALLYLBORANE; ASYMMETRIC SYNTHESIS; CHIRAL 2-BROMOHOMOALLYLIC ALCOHOLS;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The chiral bis(2,4-dimethyl-3-pentyl)tartrate ester of (2-(2-bromoallyl)boronic acid was directly prepared from the corresponding bis(2,4-dimethyl-3-pentyl) tartrate and (2-bromoallyl)diisopropoxyborane (1), obtained by the bromoboration reaction of allene. The enantioselective synthesis of 2-bromohomoallylic alcohols was achieved using the chiral (2-bromoallyl)boranes.

引用

页码：639 / 640

页数：2

共 25 条

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