MISCIBILITY OF POLY(BUTYL METHACRYLATE-CO-METHACRYLIC ACID) OR POLY(STYRENE-CO-METHACRYLIC ACID) WITH POLY(STYRENE-CO-4-VINYLPYRIDINE) OR POLY(BUTYL METHACRYLATE-CO-4-VINYLPYRIDINE)

被引：12

作者：

DJADOUN, S

KARASZ, FE

METREF, F

机构：

[1] UNIV MASSACHUSETTS, DEPT POLYMER SCI & ENGN, AMHERST, MA 01003 USA

[2] UNIV SCI & TECHNOL, INST CHEM, ALGIERS, ALGERIA

来源：

MACROMOLECULAR SYMPOSIA | 1994年 / 78卷

关键词：

D O I：

10.1002/masy.19940780115

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility of blends of copolymers of different compositions of butyl methacrylate-co-methacrylic acid or styrene-co-methacrylic acid with styrene-co-4-vinylpyridine or butyl methacrylate-co-4-vinylpyridine was studied by differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy. It was found that these blends were miscible in part as a result of specific favorable interactions between the carboxylic acid and pyridine groups within the polymer chains. Evidence of such interactions was obtained from the single composition-dependent glass transition temperature and the FTIR results.

引用

页码：155 / 169

页数：15

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