PREPARATION AND PROPERTIES OF SUPERIONIC CONDUCTING GLASSES CONTAINING LITHIUM HALIDE

被引：7

作者：

HORIUCHI, M ^{[1
]}

SEI, T ^{[1
]}

TSUCHIYA, T ^{[1
]}

机构：

[1] SCI UNIV TOKYO,FAC IND SCI & TECHNOL,NODA,CHIBA 278,JAPAN

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1994年 / 177卷

关键词：

D O I：

10.1016/0022-3093(94)90536-3

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

x(2LiCl).y(Li2O).(100-x-y)P2O5 and xAl(2)O(3).y(2LiCl).(100-x-y)P2O5 glasses were obtained for y greater than or equal to 40 mol%, and showed high ionic conduction, for example, log sigma(120 degrees C) (S/cm)= -3.58. This high conductivity was caused by the introduction of Cl- anions and amphoteric oxide (Al2O3). The proposed explanation is that the elastic strain energy, Delta H-s, decreases when large Cl- ions are introduced and the open structure that results is favorable for migration of Li+ ions.

引用

页码：236 / 241

页数：6

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