THE REEVALUATION OF MULTIPLE PEAKS IN THE DSC MELTING ENDOTHERM OF ISOTACTIC POLYPROPYLENE

被引:36
|
作者
PASSINGHAM, C
HENDRA, PJ
CUDBY, MEA
ZICHY, V
WELLER, M
机构
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
[2] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND
关键词
D O I
10.1016/0014-3057(90)90219-T
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
From X-ray, DSC and i.r. study, the appearance of multiple peaks in the melting endotherm of isotactic polypropylene has been shown to arise from α-crystalline regions alone with little influence from the β crystal form. Contrary to the appearance of the DSC thermogram, we suggest that only two genuine melting endotherms might be present and that the shape of the thermogram is modified by exothermic processes. © 1990.
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页码:631 / 638
页数:8
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