THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE

被引：71
|
作者：
ASHTON, PR [1 ]
GROGNUZ, M [1 ]
SLAWIN, AMZ [1 ]
STODDART, JF [1 ]
WILLIAMS, DJ [1 ]
机构：
[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 43期
关键词：
D O I：
10.1016/0040-4039(91)80797-A
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
X-Ray crystallography, FABMS, and H-1 and C-13 NMR spectroscopy have all been employed in the characterisation of a self-assembled [2]rotaxane composed of (i) a polyether chain intercepted by a centrally-located pi-electron rich hydroquinol ring and terminated by adamantoyl groups and (ii) a tetracationic cyclophane constructed by two pi-electron deficient bipyridinium units linked by paraphenylenedimethyl residues.
引用
收藏
页码：6235 / 6238
页数：4
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