MECHANISMS OF SUBSTITUTION OF LIGAND-BRIDGED DIIRON HEXACARBONYL COMPLEXES - (OC)3FE(MU-P(C6H5)2)2FE(CO)3 - PROMOTION OF AN SN1 MECHANISM BY A BULKY BRIDGING LIGAND

被引：13

作者：

GERLACH, JN ^{[1
]}

MCMULLIN, SL ^{[1
]}

ELLGEN, PC ^{[1
]}

机构：

[1] UNIV CALIF RIVERSIDE,DEPT CHEM,RIVERSIDE,CA 92502

来源：

INORGANIC CHEMISTRY | 1976年 / 15卷 / 05期

关键词：

D O I：

10.1021/ic50159a054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1232 / 1233

页数：2

共 50 条

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[22] STUDY OF THE REACTIVITY OF [FE2(CO)6(MU-CO)(MU-C(C6H5)C(C6H5)H)]- TOWARD THE CH3OC(O)C=CC(O)OCH3 AND CF3C=CCF3 ALKYNES - CRYSTAL-STRUCTURE OF THE PRODUCTS RESULTING FROM 2 DIFFERENT MODES OF COMBINATION OF THE ALKYNES WITH THE BRIDGING LIGANDS [FE2(CO)6(MU-C(C(O)OCH3)C(C(O)OCH3)C(O)C(C6H5)C(C6H5)H)]- AND [FE2(CO)6(MU-C(C6H5)C(C6H5)C(CF3)C(CF3)H)]-EN
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[24] INSERTION OF TETRAFLUOROETHYLENE INTO THE FE-FE BOND OF (MU(SCH3)FE(CO)3)2, ITS THERMAL REARRANGEMENT TO A BRIDGING CARBENE LIGAND, AND THE TRANSFORMATION OF THE CARBENE TO A PERFLUOROMETHYLCARBYNE LIGAND - STRUCTURES OF MU(SCH3)2MU(C2F4)FE2(CO)6 AND MU(SCH3)2MU(FCCF3)FE2(CO)6 AT 162-DEGREES-C
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[25] REACTIONS OF DINUCLEAR AND POLYNUCLEAR COMPLEXES .6. REACTION OF [(ETA-5-C5H5)(CO)FE(MU-C(CF3)=C(CF3)SME)2FE(CO)(ETA-5-C5H5)] WITH [FE3(CO)12] - LIGAND-EXCHANGE BETWEEN METALS - SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR AND TRINUCLEAR IRON ALKYNE COMPLEXES - CRYSTAL-STRUCTURE OF [(FE(CO)3)2(MU-(CF3)CCC[FE(ETA-5-C5H5)(CO)2])]
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[26] ALKYNE-INDUCED CARBYNE CARBYNE COUPLING IN THE TRINUCLEAR BIS(CARBYNE) IRON CLUSTER FE3(CO)9(MU-3-COC2H5)(MU-3-CCH3) - X-RAY STRUCTURES OF FE3(CO)6(MU-CO)2-MU-3-ETA-4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] AND FE3(CO)6(MU-CO)2-MU-3-ETA-4[C(CH3)C(OC2H5)C(SI(CH3)3)C(SI(CH3)3)]
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[27] Coordination chemistry of silver(I) with the nitrogen-bridged ligands (C6H5)2PN(H)P(C6H5)2 and (C6H5)2PN(CH3)P(C6H5)2:: The effect of alkylating the nitrogen bridge on ligand bridging versus chelating behavior
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[28] NUCLEOPHILIC-ADDITION OF CHROMIUM CARBENE ANIONS TO THE COORDINATED OLEFIN IN [CP(CO)2FE(ETA-2-OLEFIN)]+ COMPLEXES AND TO THE CYCLOHEXADIENYL LIGAND IN [(ETA-5-CYCLOHEXADIENYL)(CO)3FE]
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[29] REACTION OF [P(C6H5)4][FE2(CO)6(MU-CO)(MU-CHCH2)] WITH [RHCL(CO)2]2 - SYNTHESIS OF A TRIIRON-DIRHODIUM CLUSTER ANION CONTAINING A CH3C=C=CH2 TRIIRON-DIRHODIUM LIGAND WITH AN UNUSUAL MU-4-ETA-3 MODE OF BONDING, [P(C6H5)4][FE3RH2(CO)10(MU-CO)3(MU-4-ETA-3-CH3C=C=CH2)]
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[30] MEASUREMENT OF BARRIERS TO ARYL ROTATION IN CP(CO)2FE=CHC6H5+ AND CP(CO)2FE=CH(P-CH3C6H4)+
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