SILYLMETHYL RADICAL CYCLIZATION IN THEOPEDERINS SYNTHESIS - A NEW ACCESS TO PEDERIC ACID

被引:0
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作者
TOYOTA, M
YAMAMOTO, N
NISHIKAWA, Y
FUKUMOTO, K
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O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Silylmethyl radical cyclization of the silyl ether (6) provided the 2-silatetrahydropyran derivative (7) possessing the correct C2, C3 and C7 stereochemistries of theopederins (1) and functionalities suitable for further elaboration.
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页码:115 / 117
页数:3
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