ASPECTS OF THE CHARACTERIZATION OF CLOVERITE BY SOLID-STATE NMR TECHNIQUES

被引：14
|
作者：
ZIBROWIUS, B
ANDERSON, MW
SCHMIDT, W
SCHUTH, FF
ALIEV, AE
HARRIS, KDM
机构：
[1] UMIST,DEPT CHEM,MANCHESTER,LANCS,ENGLAND
[2] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,MAINZ,GERMANY
[3] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
来源：
ZEOLITES | 1993年 / 13卷 / 08期
关键词：
GALLOPHOSPHATE; CLOVERITE; QUADRUPOLAR COUPLING; MULTINUCLEAR MAS NMR SPECTROSCOPY; STATIC GA-71 NMR SPECTROSCOPY; LIMITATIONS OF MAS NMR SPECTROSCOPY;
D O I：
10.1016/0144-2449(93)90131-L
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Microporous gallophosphate cloverite has been studied by multinuclear (C-13, F-19, P-31, Ga-71) solid-state n.m.r. spectroscopy. An extraordinarily strong quadrupolar coupling is shown to be the reason for a misleading line shape in Ga-71 MAS n.m.r. spectra. Using static Ga-71 n.m.r. spectroscopy, an estimate of the size of this quadrupolar coupling can be obtained. The limitations of the MAS technique for the study of quadrupolar nuclei in sites with very large quadrupolar couplings are addressed.
引用
收藏
页码：607 / 610
页数：4
相关论文
共 50 条
  • [21] Experimental aspects of multidimensional solid-state NMR correlation spectroscopy
    Ramamoorthy, A
    Wu, CH
    Opella, SJ
    JOURNAL OF MAGNETIC RESONANCE, 1999, 140 (01) : 131 - 140
  • [22] Characterization of insoluble calcium alginates by solid-state NMR
    Mollica, Giulia
    Ziarelli, Fabio
    Lack, Stephane
    Brunel, Florence
    Viel, Stephane
    CARBOHYDRATE POLYMERS, 2012, 87 (01) : 383 - 391
  • [23] A solid-state NMR method for characterization of pharmaceutical eutectics
    Hareendran, Chaithanya
    Shaligram, Parth S.
    Gonnade, Rajesh
    Ajithkumar, T. G.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (05) : 3800 - 3803
  • [24] Solid-state NMR spectroscopy for characterization of acrylate reactions
    Dietz, JE
    Cowans, BA
    Scott, RA
    Peppas, NA
    PHOTOPOLYMERIZATION: FUNDAMENTALS AND APPLICATIONS, 1997, 673 : 28 - 34
  • [25] Solid-State NMR Characterization of Gas Vesicle Structure
    Sivertsen, Astrid C.
    Bayro, Marvin J.
    Belenky, Marina
    Griffin, Robert G.
    Herzfeld, Judith
    BIOPHYSICAL JOURNAL, 2010, 99 (06) : 1932 - 1939
  • [26] Solid-state carbon NMR characterization of the polymorphs of roxifiban
    Vickery, RD
    Nemeth, GA
    Maurin, MB
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2002, 30 (01) : 125 - 129
  • [27] Characterization of charcoal using advanced solid-state NMR
    Mao, Jingdong
    Pignatello, Joseph J.
    Lehmann, Johannes
    Chappell, Mark
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [28] Solid-state NMR characterization of the amorphous region of polyaniline
    Espe, MP
    Schaefer, JS
    Mattes, BR
    CONFERENCE PROCEEDINGS AT ANTEC '98: PLASTICS ON MY MIND, VOLS I-3: VOL I; PROCESSING, VOL II; SPECIAL AREAS, VOL III; MATERIALS, 1998, 44 : 1286 - 1290
  • [29] Advanced Solid-State NMR Techniques for the Study of Molecular Sieves
    Mafra, Luis
    Klinowski, Jacek
    EMAGRES, 2013, 2 (01): : 149 - 183
  • [30] Solid-State NMR Techniques for the Structural Determination of Amyloid Fibrils
    Chan, Jerry C. C.
    SOLID STATE NMR, 2012, 306 : 47 - 88
12345