The magnetic properties of CaxZnl-xFe2O4 (with x in the range 0.0 - 1.0) were investigated using Mossbauer spectroscopy and a.c. susceptibility measurements. X-ray diffraction patterns and Mossbauer data suggest that this system exists as single-phase spinel when x < 0.2 and as single-phase CaFe2O4 when x > 0.8. When samples are sintered in air, the Neel temperature of Ca0.5Zn0.5Fe2O4 is 27 K. When samples are sintered in flowing oxygen the Neel temperatures of ZnFe2O4 and Ca0.5Zn0.5Fe2O4 increase to 150 K and 205 K respectively. The room temperature resistance of the samples is reduced by three orders of magnitude when samples are quenched from 1100 K to room temperature.
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State Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Liupanshui Normal Univ, Dept Min Engn, Liupanshui 553004, Peoples R ChinaState Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Feng, Shan
Xu, Longjun
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State Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R ChinaState Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Xu, Longjun
Liu, Chenglun
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State Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400044, Peoples R ChinaState Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Liu, Chenglun
Du, Haigang
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Liupanshui Normal Univ, Dept Min Engn, Liupanshui 553004, Peoples R ChinaState Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Du, Haigang
Xie, Taiping
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State Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R ChinaState Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China
Xie, Taiping
Zhu, Qianqian
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Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400044, Peoples R ChinaState Key Lab Coal Mine Disaster Dynam & Control, Chongqing 400044, Peoples R China