MECHANISM OF THE 2-PHOTON LASER ASSISTED REACTION OF XE AND CL-2 TO FORM XECL

被引：2
|
作者：
KVARAN, A
HUASHENG, W
PETURSSON, J
机构：
[1] Science Institute, University of Iceland
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 267卷
关键词：
D O I：
10.1016/0022-2860(92)87003-E
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two-photon laser assisted reactions of Xe and Cl2 at low pressure has been used to prepare xenon chloride in excited states (XeCl*(B[1/2],C[3/2])). Dispersed luminescence spectra due to the XeCl transition, B[1/2] --> X[1/2], in the spectral region 290-310 nm were recorded for different excitation wavelengths. The vibrational energy disposal was assessed through spectral simulation of the emission spectra. The mechanism for XeCl(B) formation is discussed in terms of a simple global model.
引用
收藏
页码：13 / 19
页数：7
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