NEW ASPECTS IN THE ANIONIC-POLYMERIZATION OF PHENYL GLYCIDYL ETHER

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作者
STOLARZEWICZ, A
GROBELNY, Z
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中图分类号
O63 [高分子化学(高聚物)];
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070305 ; 080501 ; 081704 ;
摘要
A kinetic equation describing the anionic polymerization of phenyl glycidyl ether initiated by potassium anions in the presence of 18-crown-6 was derived. Rate constants of growth and chain transfer reactions were calculated. The equilibrium constant of complex formation by the active centre with alcohol being a product of chain transfer reactions was also evaluated.
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页码:531 / 538
页数:8
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