Mutual isomerization of eta(1)-allenyl and eta(1)-propargyl complexes of platinum via a five-coordinate eta(3)-allenyl/propargyl intermediate

被引：34
|
作者：
Ogoshi, S
Fukunishi, Y
Tsutsumi, K
Kurosawa, H
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期
关键词：
D O I：
10.1039/C39950002485
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reversible spontaneous isomerization between eta(1)-allenyl and eta(1)-propargylplatinum complexes is reported, which is suggested to proceed via pseudorotation of a five-coordinate eta(3)-allenyl/propargyl intermediate.
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页码：2485 / 2486
页数：2
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