IRON-CATALYZED ALLYLIC AMINATION

被引：74

作者：

JOHANNSEN, M ^{[1
]}

JORGENSEN, KA ^{[1
]}

机构：

[1] AARHUS UNIV,DEPT CHEM,DK-8000 AARHUS,DENMARK

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 01期

关键词：

D O I：

10.1021/jo00080a034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The transition-metal-catalyzed allylic amination of alkenes is studied. A screening of different transition-metal complexes reveals that iron complexes, especially iron phthalocyanin, have the best catalytic properties, using phenylhydroxylamine as the nitrogen-fragment donor. The iron phthalocyanin-catalyzed reaction has been studied for a variety of alkenes and the best yields are obtained for alkenes substituted with aromatic groups. The scope of this reaction is discussed.

引用

页码：214 / 216

页数：3

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