IRON-CATALYZED ALLYLIC AMINATION

被引：74
|
作者：
JOHANNSEN, M [1 ]
JORGENSEN, KA [1 ]
机构：
[1] AARHUS UNIV,DEPT CHEM,DK-8000 AARHUS,DENMARK
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 01期
关键词：
D O I：
10.1021/jo00080a034
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The transition-metal-catalyzed allylic amination of alkenes is studied. A screening of different transition-metal complexes reveals that iron complexes, especially iron phthalocyanin, have the best catalytic properties, using phenylhydroxylamine as the nitrogen-fragment donor. The iron phthalocyanin-catalyzed reaction has been studied for a variety of alkenes and the best yields are obtained for alkenes substituted with aromatic groups. The scope of this reaction is discussed.
引用
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页码：214 / 216
页数：3
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