OVERTONE AND HOT-BAND ASSIGNMENTS IN THE 2(NU-3, NU-6) LEVELS OF CHD3

被引：5
|
作者：
ROCHE, C
CHAMPION, JP
COY, SL
KLAASSEN, JJ
STEINFELD, JI
VALENTIN, A
MIZUGAI, Y
JOHNS, JWC
机构：
[1] UNIV BOURGOGNE,SPECT MOLEC & INSTRUMENTAT LASER LAB,CNRS,UNITE 777,F-21000 DIJON,FRANCE
[2] MIT,GR HARRISON SPECTROSCOPY LAB,CAMBRIDGE,MA 02139
[3] MIT,DEPT CHEM,CAMBRIDGE,MA 02139
[4] UNIV PARIS,PHYS MOLEC & APPLICAT LAB,PARIS,FRANCE
[5] SOPHIA UNIV,FAC SCI & TECHNOL,TOKYO 102,JAPAN
[6] NATL RES COUNCIL CANADA,HERZBERG INST ASTROPHYS,OTTAWA K1A 0R6,ONTARIO,CANADA
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 08期
关键词：
D O I：
10.1063/1.467169
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Assignments have been carried out for the 2nu3/(nu3+nu6)/2nu6 (triad)<--ground state overtone bands and the triad<--nu3/nu6 hot-band system of CHD3. A vibrational extrapolation method, using correspondences between a spherical-tensor formalism and the more conventional description of symmetric-rotor spectra, was used to facilitate the assignment and analysis of these bands. The resulting assignments have been confirmed by time-resolved double-resonance measurements.
引用
收藏
页码：5508 / 5518
页数：11
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