PREPARATION, CHARACTERIZATION AND REACTION OF THE FIRST DIOXORUTHENIUM(VI) COMPLEXES OF CHIRAL PICKET-FENCE PORPHYRINS

被引：23
|
作者：
LEMAUX, P
BAHRI, H
SIMONNEAUX, G
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 11期
关键词：
D O I：
10.1039/c39940001287
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Preparation and characterization of dioxoruthenium(vi) picket-fence complexes bearing optically active alpha-methoxy-alpha(trifluoromethyl)phenylacetyl residues on both sides of the porphyrin plane (alpha,beta,alpha,beta and alpha,alpha,beta,beta isomers) are described oxidation of racemic benzyl(methyl)(phenyl)phosphine by the alpha,beta,alpha,beta isomer leads to the formation of optically active phosphine oxide (enantiomeric excess 41%) and proceeds with retention of the configuration of the phosphorus atom.
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收藏
页码：1287 / 1288
页数：2
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