Site-selection spectroscopy and energy transfer studies of Eu3+ ions in a new fluorophosphate glass

被引:2
|
作者
Balda, R
Fernandez, J
Duhamel, N
Adam, JL
Imbusch, GF
机构
[1] UNIV BASQUE COUNTRY, DEPT FIS APLICADA 1, E-48013 BILBAO, SPAIN
[2] UNIV RENNES, LAB VERRES & CERAM, F-35042 RENNES, FRANCE
[3] NATL UNIV IRELAND UNIV COLL GALWAY, GALWAY, IRELAND
关键词
D O I
10.1016/0022-2313(95)00155-7
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The spectral migration of the time-resolved resonant line-narrowed D-5(0) --> F-7(0) emission band of Eu3+ in a new fluorophosphate glass of compositions (in mol%) 60NaPO(3)-15BaF(2)-(25-x)YF3-xEuF(3) (x = 0.5, 2, 5, 10, 15, 20, 25) has been investigated. The results may be interpreted in terms of a dipole-dipole energy transfer mechanism between the distributions of Eu3+ centers. Analysis of the measured fluorescence decays of the D-5(0) state suggest that the transfer process is Fast enough to drive the system of excited centers to thermal equilibrium.
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页码:290 / 293
页数:4
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