A SIMPLE, EFFECTIVE, NEW, PALLADIUM-CATALYZED CONVERSION OF ENOL SILANES TO ENONES AND ENALS

被引：186
|
作者：
LAROCK, RC [1 ]
HIGHTOWER, TR [1 ]
KRAUS, GA [1 ]
HAHN, P [1 ]
ZHENG, D [1 ]
机构：
[1] IOWA STATE UNIV SCI & TECHNOL,TOXICOL PROGRAM,AMES,IA 50011
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 14期
关键词：
D O I：
10.1016/0040-4039(95)00306-W
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Enol silanes derived from aldehydes and ketones are readily converted to the corresponding alpha,beta-unsaturated carbonyl compounds by 10% Pd(OAc)(2) in the presence of one atmosphere of oxygen in DMSO as the solvent.
引用
收藏
页码：2423 / 2426
页数：4
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