REACTIONS OF TRIS-DIIMINE AND DIIMINE-CYANIDE COMPLEXES OF IRON(II) WITH PEROXOANIONS IN SOLUTION

被引：6

作者：

BURGESS, J ^{[1
]}

SHRAYDEH, B ^{[1
]}

机构：

[1] ANNAJAH NATL UNIV,NABLUS,ISRAEL

来源：

POLYHEDRON | 1992年 / 11卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)83156-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Investigations of the kinetics of reactions of low-spin iron(II)-diimine-cyanide complexes with peroxodiphosphate, peroxoborate and peroxomonosulphate suggested that only the last-named could act by rate-determining oxidation. Peroxodiphosphate and perborate react by rate-limiting dissociation with the subsequent rapid oxidation of the products of this dissociation. The reactivity trend for peroxomonosulphate oxidation of the [Fe(CN)4(bipy)]2- anion in water-acetonitrile mixtures is reported, and analysed into initial state and transition state contributions with the aid of appropriate assumptions.

引用

页码：2015 / 2019

页数：5

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