REACTIONS OF TRIS-DIIMINE AND DIIMINE-CYANIDE COMPLEXES OF IRON(II) WITH PEROXOANIONS IN SOLUTION

被引：6
|
作者：
BURGESS, J [1 ]
SHRAYDEH, B [1 ]
机构：
[1] ANNAJAH NATL UNIV,NABLUS,ISRAEL
来源：
POLYHEDRON | 1992年 / 11卷 / 16期
关键词：
D O I：
10.1016/S0277-5387(00)83156-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Investigations of the kinetics of reactions of low-spin iron(II)-diimine-cyanide complexes with peroxodiphosphate, peroxoborate and peroxomonosulphate suggested that only the last-named could act by rate-determining oxidation. Peroxodiphosphate and perborate react by rate-limiting dissociation with the subsequent rapid oxidation of the products of this dissociation. The reactivity trend for peroxomonosulphate oxidation of the [Fe(CN)4(bipy)]2- anion in water-acetonitrile mixtures is reported, and analysed into initial state and transition state contributions with the aid of appropriate assumptions.
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页码：2015 / 2019
页数：5
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