STEREOSPECIFICITY AND STEREOSELECTIVITY IN THE [3,2] SIGMATROPIC REARRANGEMENT OF OPEN-CHAIN SULFONIUM YLIDES

被引：11

作者：

HARTLEY, RC

WARREN, S

机构：

[1] UNIV CAMBRIDGE,CHEM LABS,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] SCHERING AGROCHEM LTD,CHESTERFORD PK RES STN,SAFFRON WALDEN CB10 1XL,ESSEX,ENGLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)74746-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The [3,2] sigmatropic rearrangement of sulphonium ylides derived from allyl sulphides with 1,2-related chiral centres was carried out with excellent stereochemical control. 1,4-Related chiral centres across an E double bond are set up stereospecifically by this reaction and good 4,5 diastereoselectivity is observed.

引用

页码：8155 / 8158

页数：4

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